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Zur Kenntnis des Pentaphosphacyclopentadienid-Ions, P

✍ Scribed by Prof. Dr. Marianne Baudler; Stilianos Akpapoglou; Dimitrios Ouzounis; Prof. Dr. Fritz Wasgestian; Bernd Meinigke; Prof. Dr. Herbert Budzikiewicz; Helmut Münster


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
218 KB
Volume
100
Category
Article
ISSN
0044-8249

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The configuration of C-2 of 8 arises because in the transition state 13 the ester function gives way to the bulky dioxolane ring and therefore occupies exchiuely the exo position (cf., however, Ref. [I]).-If the dioxolane ring in 13 is replaced by the smaller methyl group, i.e., in the transition st

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Contributions to the Chemistry of Phosphorus, 215. – Simple Preparation of the Pentaphosphacyclopentadienide Ion, __cyclo__‐P^⊖^~5~, by Degradation of Red Phosphorus with Potassium Dihydrogenphosphide The pentaphosphacyclopentadienide ion 1 is easily obtained in the form of a KP~5~ solution by the

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