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Zur Kenntnis der sogenannten «Alkalicarbonyle» III. Die «Alkalicarbonyle» als Substangemische einer metalloganischen Verbindung und Metallacetylendiolaten

✍ Scribed by W. Büchner


Publisher
John Wiley and Sons
Year
1963
Tongue
German
Weight
703 KB
Volume
46
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The pyrophoric products obtained from the alkalimetals lithium, sodium, potassium, rubidium, and cesium with carbon monoxide in liquid ammonia are shown to be mixtures of the metal acetylene diolates, MOC  COM, with an organometallic compounds, the possible structures of which are discussed.