Zur Kenntnis der Hexaalkylbenzole. 1. Mitteilung. Anomale FRIEDEL-CRAFTS-Reaktionen von Hexaäthyl- und Hexamethylbenzol

✍ Scribed by H. Hopff; A. K. Wick

• Publisher: John Wiley and Sons
• Year: 1960
• Tongue: German
• Weight: 679 KB
• Volume: 43
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19600430604

✦ Synopsis

Abstract

An anomalous type of FRIEDEL‐CRAFTS reaction was observed with hexaethyland hexamethylbenzene. With a number of acid chlorides and γ‐dicarboxylic anhydrides the reaction proceeded by elimination of an alkyl group with production of the corresponding pentaalkylphenyl ketones and γ‐pentaalkylbenzoyl acids respectively.