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Zur Frage der Existenz isomerer, äquatorial koordinierter 1:2-Co(III)-Komplexe aus symmetrischen o, o'-Dihydroxyazofarbstoffen

✍ Scribed by Guido Schetty


Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
294 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

2,2′‐Dihydroxy‐3,3′‐dimethyl‐5,5′‐di‐t‐butyl‐1,1′‐azobenzene has been metallized to the 1 : 2‐Co‐(III)‐complex. In addition to the main product a further complex was isolated by chromatography in a yield of about 2% and proved to be an isomer of the main complex. The cause of the isomerism could not be elucidated.