✦ LIBER ✦
Zur elektronenstruktur metallorganischer komplexe der ƒ-elemente—XXIV. Interpretation der optischen und magnetochemischen Eigenschaften von Cp3CeIII THF auf der Grundlage der kristallfeldtheorie
✍ Scribed by H. Reddmann; H. Schultze; H.-D. Amberger; C. Apostolidis; B. Kanellakopulos
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 594 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1386-1425
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✦ Synopsis
On
the basis of magnetic susceptibility, NMR spectroscopic and optical measurements the crystal field splitting pattern of ($-C,H&Ce 'n*THF could be derived. The free parameters of an empirical Hamiltonian were fitted to the experimentally derived crystal field splitting pattern. Making use of the calculated crystal field eigenvalues, the magnetochemical data could be reproduced in a satisfactory manner.