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Zur Deutung der thermodynamischen Daten von Komplexbildungsreaktionen I

✍ Scribed by G. Anderegg

Publisher
John Wiley and Sons
Year
1968
Tongue
German
Weight
517 KB
Volume
51
Category
Article
ISSN
0018-019X

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✦ Synopsis

The free enthalpy of complex formation, corrected for the involved change of the number of particles, is described as a sum: AG,,+AG,, (= AG-AG,), which permits the separation of the temperature dependent terms. Following GURNEY, it is supposed that the temperature dependent free enthalpy AG,, varies in the same way as the reciprocal of the dielectric constant of the solvent. This model furnishes some relations which permit a correct description of the complex formation in terms of an electrovalent and of a nonelectrovalent interaction.

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