𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Zur Biogenese des Antibioticums Phomin. 1. Teil: Die Grundbausteine

✍ Scribed by M. Binder; J.-R. Kiechel; Ch. Tamm


Publisher
John Wiley and Sons
Year
1970
Tongue
German
Weight
886 KB
Volume
53
Category
Article
ISSN
0018-019X

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Die konkurrierende 1,2- und 1,3-Acylwand
✍ C. A. Grob; C. Wagner 📂 Article 📅 1955 🏛 John Wiley and Sons 🌐 German ⚖ 573 KB

## Abstract Reversible 1,2 and 1,3 acyl migrations with retention of configuration are shown to occur in 2‐hydroxy‐3,4‐diamino‐pentane. In 2‐hydroxy‐3,4‐bis(acetylamino)‐pentane, where 1,2 and 1,3 migration of like acyl groupe compete, the former reaction was the only one observed. In 2‐hydroxy‐3‐b