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Zirconocene-Induced Cocyclization/Elimination Reactions of 2-Heterosubstituted 1,6-Dienes and 1,6-Enynes.

✍ Scribed by David R. Owen; Richard J. Whitby


Publisher
John Wiley and Sons
Year
2005
Weight
42 KB
Volume
36
Category
Article
ISSN
0931-7597

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Palladium-catalyzed cyclizations of the 2-bromo-1,6-diene 6 57 with a methoxycarbonyloxymethylene substituent on the triple bond gave in 36% yield the 2,3-bis(bicyclo[3.1.0]hex-with an acetoxymethyl substituent on the bromoalkenyl moiety did not only lead to the expected 1-acetoxymethyl-1-yl)-substi