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Zirconium and dichlorotin(iv) salts of 3,4,5,6-tetrahydro-2H-azepin-7-OL hydrogen sulfate, highly effective catalysts for the Beckmann rearrangement of cyclohexanone oxime

✍ Scribed by M. Masaki; J. Kita; K. Fukui; S. Matsunami


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
209 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


In the Beckmann rearrangement of ketoximes to amides using a rearranging agent containing sulfur trioxide moiety, e.5. such as sulfuric acid, 1) oleum,l) or sulfur trioxide-Lewis base complex, 2) it is well known that the agent is in