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Zinc‐Catalyzed Hydrogenative Cleavage of Azo Compounds Using Triethylammonium Formate

✍ Scribed by Srinivasa, G. R.; Abiraj, K.; Channe Gowda, D.


Book ID
120200826
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
147 KB
Volume
34
Category
Article
ISSN
0094-5714

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Reductive cleavage of azo compounds cata
✍ Shankare Gowda; K Abiraj; D.Channe Gowda 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 56 KB

Azo compounds, both symmetric and unsymmetric, are cleaved to amine(s) by using commercial zinc dust and ammonium formate or formic acid in methanol, tetrahydrofuran or dioxane at room temperature. The reductive cleavage occurs without hydrogenolysis or hydrogenation of reducible moieties, such as -