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Zinc-promoted reactions. 8. The effect of ring strain in the reduction of 1,2-dibenzoylcycloalkanes

โœ Scribed by Maria Luisa di Vona; Luciana Luchetti; Vittorio Rosnati

Book ID
104204314
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
350 KB
Volume
50
Category
Article
ISSN
0040-4020

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Regioselectivity in the reductive ring-o
Regioselectivity in the reductive ring-opening reaction of 1,2-O-benzylidene sugars
โœ Katsuhiko Suzuki; Hisato Nonaka; Masanori Yamaura ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 89 KB

Regioselectivity in the ring-opening reaction of 1,2-O-benzylidene sugars was studied. In the reductive ring-opening reaction of 1,2-O-benzylidene derivatives, only a C O1 bond was cleaved in the case of manno-type, but both the C O1 and C O2 bonds were cleaved in the case of gluco-type.