Zinc-mediated Reductive Dimerization Cyclization of Ethyl Arylmethylidene cyanoacetates in Aqueous Media
β Scribed by Wang, Lei; Zhang, Yongmin
- Book ID
- 120689831
- Publisher
- Science Reviews 2000 Ltd
- Year
- 1999
- Tongue
- English
- Weight
- 97 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0308-2342
- DOI
- 10.1039/A900711C
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In saturated NH4CI (aq.)-THF solution at room temperature, metallic samarium promoted reductive dimerization cyclization of gem-diactivated alkenes, reductive debromination of vic-dibromides, and reduction of sodium alkyl thiosulfates occur to afford corresponding functionalized cyclopentenes, (E)-a
## Abstract Zinc powderβmediated reductive cyclization of __o__βnitrophenylazophenols in alkaline solution affords the corresponding 2βarylβ2__H__βbenzotriazoles in high yields under mild reaction conditions. __No organic solvents__ are used in the reaction and only minimal amounts in the workβup.