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Zinc-mediated Barbier reactions of pyrrole and indoles: a new method for the alkylation of pyrrole and indoles

✍ Scribed by J.S. Yadav; B.V.S. Reddy; P.Muralikrishna Reddy; Ch. Srinivas

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
155 KB
Volume
43
Category
Article
ISSN
0040-4039

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## Abstract The transition structures for MacMillan's alkylations of __N__‐methylpyrrole by aldehydes catalyzed by chiral amine salts were explored with B3LYP/6‐31G(d) density functional theory. These results provide an explanation of the enantioselectivities observed with these two catalysts.