Zinc (II), cadmium (II) and mercury (II) complexes of 2-methyl-benzothiazole

✍ Scribed by Giorgio Peyronel; Aleardo Giusti

• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 482 KB
• Volume: 37
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(81)80090-6

✦ Synopsis

The following zinc (II), cadmium (II) and mercury (II) complexes of 2-methyl-benzothiazole (2Mebt = L) have been prepared and studied by conductometric methods, i.r. and Raman spectra: ML2X 2 (M=Zn, X=CI, I, NO3; M=Cd, X=NO3, C104; M=Hg, X=NO3) , ML1.5X 2 (M=Zn, X=C104 (H20); M=Hg, X=C104) and MLX 2 (M=Cd and Hg, X=C1, Br, I). The ligand is N-bonded when acting as monodentate and N,S-bonded as bridging ligand. The halide, nitrate and perchlorate ions are coordinated.