Zinc anilido-oxazolinate complexes as initiators for ring opening polymerization
β Scribed by Chen, Chi-Tien; Chan, Chi-Yu; Huang, Chi-An; Chen, Ming-Tsz; Peng, Kuo-Fu
- Book ID
- 121400459
- Publisher
- Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 175 KB
- Volume
- 36
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/B705398C
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π SIMILAR VOLUMES
## Abstract The ringβopening polymerization (ROP) of __Ξ΅__βcaprolactone (__Ξ΅__βCL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(ΞΌβSPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini
Phosphoraneiminato complexes of transition metals containing the NPR 3 Γ group are known in many coordinationchemical variations [1] as a result of varying bonding modes. In complexes with metal ions in low oxidation states (i, ii) the NPR 3 Γ group acts as m 3 -N bridging ligand, in medium oxidati