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Ziegler-type systems as catalysts for hydrosilylation: linear dimerisation with terminal acetylenes

✍ Scribed by Lappert, M. F.; Takahashi, S.

Book ID
120828078
Publisher
The Royal Society of Chemistry
Year
1972
Tongue
English
Weight
147 KB
Volume
23
Category
Article
ISSN
0022-4936

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Ziegler-type catalysts in the system Cp2
Ziegler-type catalysts in the system Cp2TiCl2/ethyl aluminium chloride with methylene chloride as solvent. Explanation of the β€œlinear” uptake of ethylene
✍ J.C. Evans; P.H. Morgan πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 88 KB

Abstrae~The paper gives an explanation for the "linear" uptake of ethylene by a polymerisation process, wrongly observed by Yildirim working on a CpzTiCI2/AI2Et3CI3/CH:CI 2 system. A comment is also made on the interpretation of electron spin resonance spectra.