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Zero-phonon photochemistry of hydrogen bonded hyroxy quinones as studied by photochemical hole burning

✍ Scribed by F. Graf; H.-K. Hong; A. Nazzal; D. Haarer


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
481 KB
Volume
59
Category
Article
ISSN
0009-2614

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✦ Synopsis


It is shown that several hydroxy q&ones undergo photochemical transformation at low temperatures (1.8 K). This phenomenon, which is investigated by photochemical hole burning, is shown to be extremely matrix dependent. From spectroscopic data and from CNDO model calculations iP is concluded that the photochemical process involves both intramolecular and intermolecular hydrogen bonds.