Cr(III), Fe(III) and Bi(III) complexes of N,N -bis(salicylidene)diethylenetriamine (H 2 saldien) encapsulated in zeolite-Y have been isolated and characterised by spectroscopic (IR and UV-Vis) studies and thermal as well as X-ray diffraction (XRD) patterns. Catalytic activities of these complexes fo
Zeolite-encapsulated Cr(III), Fe(III), Ni(II), Zn(II) and Bi(III) salpn complexes as catalysts for the decomposition of H2O2 and oxidation of phenol
β Scribed by M.R. Maurya; S.J.J. Titinchi; S. Chand; I.M. Mishra
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 108 KB
- Volume
- 180
- Category
- Article
- ISSN
- 1381-1169
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Interaction of excess of N,N -bis(salicylidene)diethylenetriamine (H 2 saldien) with Cu(II), Ni(II) and Zn(II) exchanged zeolite-Y at ca. 90 β’ C leads to the encapsulation of ligand in the super cages of zeolite followed by complexation with metal ions. These encapsulated metal complexes have been c
## Abstract The kinetics of the H~2~O~2~ decomposition by Cu(II)β, Co(II)β, and Fe(III)βamine complexes supported on the surface of silicaβalumina (25% Al~2~O~3~) catalyst have been investigated. The decomposition process proceeded with firstβorder kinetics for the substrate concentration. With cop