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Z-Selective intramolecular Horner–Wadsworth–Emmons reaction for the synthesis of macrocyclic alkenes

✍ Scribed by Kaori Ando; Kaori Sato

Book ID: 104098832
Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 368 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.01.043

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✦ Synopsis

The Z-selective intramolecular Horner-Wadsworth-Emmons reaction of the substrates 7-12 (RO) 2 P(O)CHR 0 CO 2 Et (R 0 = (CH 2 ) n CHO) (R = Ph or o-tBuC 6 H 4 ) gives the 13-18-membered cyclic alkenes

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