In the title compound, C~10~H~6~FNO~2~S, the benzene and thiazolidine rings are oriented at a dihedral angle of 8.90 (3)°. Intramolecular C—H...O, C—H...F and C—H...S hydrogen bonds result in the formation of two nearly planar five-membered rings and one non-planar six-membered ring, the five-member
(Z)-5-(2-Chlorobenzylidene)thiazolidine-2,4-dione
✍ Scribed by Sun, Hong-shun ;He, Wei ;Xu, Ye-ming ;Tang, Shi-gui ;Guo, Cheng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 670 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C~10~H~6~ClNO~2~S, the benzene and thiazolidine rings are oriented at a dihedral angle of 14.22 (5)°. Intramolecular C—H...O, C—H...Cl and C—H...S hydrogen bonds result in the formation of two nearly planar five-membered rings and one nonplanar six-membered ring, the five-membered rings being also nearly coplanar with the adjacent rings. In the crystal structure, intermolecular N—H...O hydrogen bonds link the molecules.
📜 SIMILAR VOLUMES
In the title compound, C~10~H~6~N~2~O~4~S, the benzene and thiazolidine rings are oriented at a dihedral angle of 8.8 (5)° to one another. In the crystal structure, intramolecular C—H...O and C—H...S hydrogen bonds are present; intermolecular N—H...O and C—H...O hydrogen bonds link the molecules int
There are two molecules in the asymmetric unit of the title compound, C 21 H 12 Cl 4 N 2 O 2 S 3 , which differ in the orientation of the chlorobenzene ring.
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.002 A R factor = 0.039 wR factor = 0.100 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.