The planar molecules of the title compound, C 15 H 13 FO 2 , are normal. The non-centrosymmetric crystal packing may be influenced by weak C-HÁ Á ÁO and C-HÁ Á ÁF interactions.
(Z)-1,4-Bis(4-methoxyphenyl)-2-(methylsulfanyl)but-2-ene-1,4-dione
✍ Scribed by Chen, Ai-Hua ;Wang, Zhi-Guo ;Gao, Meng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 115 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 19 H 18 O 4 S, displays a trans configuration with respect to the central C C double bond. The dihedral angle between the two aromatic rings is 81.67 (5) .
📜 SIMILAR VOLUMES
The enone group and the benzene rings of the title compound, C 16 H 13 NO 4 , are each planar. In the crystal structure, intermolecular C-HÁ Á ÁO interactions form chains along the a axis.
The title compound, C 28 H 18 Cl 6 , was obtained by the electrolysis of 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethane (DDT) in the presence of a catalytic amount of the cobalamin derivative heptamethyl cobyrinate perchlorate. The alkene group of the molecule has a Z configuration.
In the title compound, C 17 H 16 O 3 , the dihedral angle between the benzene rings is 10.05 (9) . Intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules to form chains along the b axis. The crystal structure is further stabilized by C-HÁ Á Á interactions.