Yttrium(III) oxoisopropoxide: A new synthetic route and reinvestigation of the 1H, 13C and 89Y NMR of Y5(μ5-O)(μ3-OiPr)4(μ2-OiPr)4(O iPr)5
✍ Scribed by Catherine J. Page; Sandip K. Sur; Mark C. Lonergan; Gyanendra K. Parashar
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 382 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Yttrium(III) oxoisopropoxide, Y~5~O(O^i^Pr)~13~, was synthesized via a new synthetic route and characterized by mass spectrometry and multinuclear magnetic resonance spectroscopic techniques. Extensive ^1^H, ^13^C and ^89^Y NMR studies with full assignments are reported.
📜 SIMILAR VOLUMES
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.