Yttrium and Lanthanide Diphosphanylamides: Syntheses and Structures of Complexes with one {(Ph2P)2N}− ligand in the Coordination Sphere
✍ Scribed by Peter W. Roesky; Michael T. Gamer; Nicolas Marinos
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 152 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo