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Ytterbium triflate catalysed Meerwein–Ponndorf–Verley (MPV) reduction

✍ Scribed by Adriano Mollica; Salvatore Genovese; Francesco Pinnen; Azzurra Stefanucci; Massimo Curini; Francesco Epifano

Book ID
113930389
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
407 KB
Volume
53
Category
Article
ISSN
0040-4039

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## Abstract The new variation of the Meerwein‐Ponndorf‐Verley reduction using 1‐[4‐(dimethylamino)phenyl]ethanol (DMAPE) (6) or 1‐tetralol (12) (3 equiv.) as the reducing alcohols and Zr(O‐__t__Bu)~4~ as the catalyst (0.2 equiv.) is kinetically controlled and highly stereoselective. Preferential ax