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Y(NO3)3·6H2O catalyzed regioselective ring opening of epoxides with aliphatic, aromatic, and heteroaromatic amines

✍ Scribed by Mayur J. Bhanushali; Nitin S. Nandurkar; Malhari D. Bhor; Bhalchandra M. Bhanage


Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
180 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis


Yttrium nitrate hexahydrate [Y(NO 3 ) 3 Á6H 2 O] was found to be an efficient catalyst for selective ring opening of epoxides with aliphatic, aromatic, and heteroaromatic amines at room temperature under solvent-free conditions. The system tolerated a variety of hindered and functionalized epoxides/amines and afforded the desired b-amino alcohols at low catalyst concentration.


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