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Yield of 16OS18O from the 18OH initiated oxidation of CS2 in 16O2

✍ Scribed by Edward R. Lovejoy; A. R. Ravishankara; Carleton J. Howard

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 564 KB
Volume: 26
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550260508

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✦ Synopsis

The yield of l60Sl8O from the "OH initiated oxidation of CS2 in l 6 0 2 was measured by using a discharge flow reactor coupled to a chemical ionization mass spectrometer. 1sOS180 is the dominant SO2 isotopomer produced with a yield of 0.90 2 0.20 relative to 180H loss. The errors are estimates for the uncertainty at the 95% confidence level. The implications of these results to the understanding of the CS2 oxidation mechanism are discussed. 0

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