Yb–Zn–Al ternary system: CaCu5-type derived compounds in the zinc-rich corner

✍ Scribed by Maria Luisa Fornasini; Pietro Manfrinetti; Donata Mazzone

• Book ID: 104029583
• Publisher: Elsevier Science
• Year: 2006
• Tongue: English
• Weight: 962 KB
• Volume: 179
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1016/j.jssc.2006.03.040

✦ Synopsis

Zn 22 type, was refined from powder data by the Rietveld method. The four structures belong to the same family, derived from the CaCu 5 type by replacing totally or partially some Ca atoms with dumbbells of partner elements. All the structures show no order for the aluminium atoms, but they preferentially occupy the dumbbells sharing the sites with zinc.