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Yb(OTf)3 catalyzed highly regioselective allylation of aromatic epoxides: an efficient route to bishomoallyl alcohols

✍ Scribed by Pravin R. Likhar; Manyam Praveen Kumar; Ananda K. Bandyopadhyay


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
65 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


Anhydrous ytterbium(III) triflate-catalyzed ring opening of aromatic 1,2-epoxides with allyltributyltin in THF results in the formation of bishomoallyl alcohols in excellent yields and with complete regioselectivity. The results are compared with those obtained with allylmagnesium bromide as allylating agent.


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ChemInform Abstract: Yb(OTf)3-Catalyzed
✍ Pravin R. Likhar; Manyam Praveen Kumar; Ananda K. Bandyopadhyay πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 1 views

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