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Yb(OTf)3-catalyzed C-glycosylation: highly stereoselective synthesis of C-pseudoglycals

โœ Scribed by Mohamed Takhi; Adel A.-H Abdel Rahman; Richard R Schmidt


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
104 KB
Volume
42
Category
Article
ISSN
0040-4039

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InCl3-catalyzed stereoselective synthesi
โœ J.S Yadav; B.V.S Reddy; J.V Raman; N Niranjan; S Kiran Kumar; A.C Kunwar ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

Glycals react smoothly with furan in the presence of a catalytic amount of indium trichloride at ambient temperature to afford predominantly the C-3-substituted glycals in high yields. Other heteroaromatics including 2-benzyloxymethylfuran, thiophene and N-Boc protected indole afford exclusively C-1