The thin hydrous manganese oxide electrodeposited on gold has been studied using X-ray Photoelectron Spectroscopy (XPS). The oxygen 1s spectrum changes during the cathodic discharge process and can be deconvoluted into three components: Mn=O, MnOH or Mn-OH, and water adsorbed. The surface compositi
XPS study of MnO2 minerals treated by bioleaching
β Scribed by V. Di Castro; G. Polzonetti; G. Contini; C. Cozza; B. Paponetti
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 326 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0142-2421
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β¦ Synopsis
Abstract
XPS has been used to follow the change of the ore surface composition during bioleaching with a mixed culture of microorganisms. In the original sample, the presence of MnO~2~ together with silica and alumina is observed. During bioleaching, Mn(IV) is progressively reduced to Mn(II) and signals due to the presence of the microorganisms appear in the C 1s and N 1s spectra.
In the residual sample, a considerable amount of Mn associated with the cells of the microorganisms of reprecipitated in the from of the Mn(OH)~2~ is present on the surface of the ore. This Mn species can be removed completely by treatment with a dilute soultion of HCI.
π SIMILAR VOLUMES
First-principles quantum chemical calculations have been used to reproduce S 2p x-ray photoelectron spectroscopy binding energies for a number of sulphide minerals where accurate experimental data are available. Periodic calculations have been performed with the Hartree-Fock/density functional hybri
## Abstract The O 1s line of an ordinary, untreated glass surface and of a glass surface in its dealkalized state were studied by XPS. One single O 1s peak was detected on the dealkalized sample at a binding energy (BE) of 532.5 eV while on the alkaliβcontaining sample, and also on the dealkalized