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Xe2Cl and Kr2F excited state (4 2Γ) absorption spectra: measurements of absolute cross sections

✍ Scribed by D.B. Geohegan; J.G. Eden

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
542 KB
Volume
139
Category
Article
ISSN
0009-2614

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✦ Synopsis

Absolute absorption cross sections for the lowest excited states (4 'I ) of Xe,Cl and Rr2F have been measured at discrete wavelengths in the visible and ultraviolet ( Xe,Cl: 325 6 I < 495 nm; KrZF: 248 Q I Q 570 nm ) The wavelengths observed for the 9 'I +4 'I band peak in each spectrum confirm the predictions of theory. However, the spectral profile and magnitude of the Xe,CI and Kr2F absorption cross sections are considerably different from those predicted theoretically for the corresponding rare gas dimer ions, Xe$ and Kr,+ .

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