The crystal structure of the chalcogenide compounds CuFeAlSe 3 and CuFeGaSe 3 , belonging to the system I-II-III-III 3 , were characterized using X-ray powder diffraction data. Both compounds crystallize in the tetragonal space group P42c (NΒΊ 112), Z = 1, with unit cell parameters a = 5.609(1) Γ , c
X-Rays and DTA of CuFeGaSe3 and CuFeInSe3 Quaternary Compounds
β Scribed by Grima Gallardo, P. ;Ruiz, J.
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 158 KB
- Volume
- 173
- Category
- Article
- ISSN
- 0031-8965
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β¦ Synopsis
CuFeGaSe 3 and CuFeInSe 3 materials were prepared by the usual melting and annealing technique. X-ray photographs show a tetragonal structure with lattice parameters a = (5.639 AE 0.003) # e, c = (11.13 AE 0.02) # e, c/a = 1.974 and a = (5.761 AE 0.001) # e, c = (11.497 AE 0.009) # e, c/a = 1.996, respectively. DTA analysis gives melting points of 1304 and 1210 K, respectively.
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The multiferroic compounds Bi 0.9 Sm 0.1 FeO 3 , Bi 0.9 Gd 0.1 FeO 3 , Bi 0.9 Ca 0.1 FeO 3 , Bi 0.9 Sm 0.05 Ca 0.05 FeO 3 , and Bi 0.9 Gd 0.05 Ca 0.05 FeO 3 were prepared by the conventional ceramic method and were characterized by X-ray diffraction, vibrating sample magnetometry, and differential s