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X-ray study of the low-temperature phase of [NaMn3+3](Mn3+2Mn4+2)O12, a perovskite-like compound

โœ Scribed by J. Chenavas; F. Sayetat; A. Collomb; J.C. Joubert; M. Marezio

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
237 KB
Volume
16
Category
Article
ISSN
0038-1098

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โœ A.L. Barra; Andrea Caneschi; Dante Gatteschi; David P. Goldberg; Roberta Sessoli ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 134 KB

The high-5eld EPR spectra of a mixed valence cluster compound of formula [Et 3 NH] 2 [Mn(CH 3 CN) 4 (H 2 O) 2 ] [Mn 10 O 4 (biphen) 4 Br 12 ] con5rm that the high-spin ground state (S โ€ซุโ€ฌ 12) of the cluster has a negative zero-5eld splitting, D โ€ซุŠุโ€ฌ 0.037(1) cm ุŠ1 . The reversal of the magnetization