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X-ray study of a mixed indium chalcogenide In∼2.01 X3 (X = S, Se, Te): The occurrence of indium(I) in indium(III) chalcogenides

✍ Scribed by C. Svensson; J. Albertsson


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
703 KB
Volume
46
Category
Article
ISSN
0022-4596

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The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]•0.75 C 6 H 6 (2) and the unexpected pentacoordinat