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X-Ray Studies of Rare Earth Oxide Systems. II. The Oxide Systems Ce IV -Sm III , Ce IV -Gd III , Ce IV -Y III , Pr IV -Y III and Pr III -Y III

✍ Scribed by McCullough, J. D.; Britton, J. D.


Book ID
126334971
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
409 KB
Volume
74
Category
Article
ISSN
0002-7863

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Studies of the Ce(III)/Ce(IV) couple in
✍ Derek Pletcher; Erika M. Valdes πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 714 KB

The factors influencing the transfer of Ce(IV) from aqueous solutions to organic solvents using either tetrabutylammonium ion or trihutylphosphate as the extractant are investigated. It is shown that extraction is efficient from acidic nitrate solutions but that other anions, particularly sulphate d

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It is confirmed that in divided cells, the oxidation of Ce(III) to Ce(IV) is possible with good current efficiency in many electrolytes. On the other hand, it is difficult to achieve such efficiency in undivided cells but it is possible using an emulsion of nitric acid/n-hexane containing tributylph