X-ray Structure of a Trimeric 5,5′-Biaryl/erythro-β-O-4-ether Lignin Model: Evidence for Through-Space Weak Interactions
✍ Scribed by Jean-Philippe Roblin; Hubert Duran; Elisabeth Duran; Liliane Gorrichon; Bruno Donnadieu
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 161 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0947-6539
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✦ Synopsis
The crystal structure of a trimeric lignin model 1 presenting the characteristic pattern of biphenyl (5,5') and aryl-alkyl-ether (b-O-4) linkages has been determined. The crystal system is triclinic and the crystallographic unit cell consists of two monomeric molecules. These results are compared with crystal data from the literature of simple models of the 5,5' and b-O-4 structure type. The availability of a terminal aldehyde function on the model affords some interesting intermolecular interactions by weak hydrogen bonding which controls the conformation of the molecule and the aromatic ring orientation in particular; an unexpected cisoïd conformation of the biaryl unit is observed based on the 64.48 value found for the torsion angle between the two 5,5' aromatic rings.