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X-Ray Structure Investigation of 2,2-Diphenyl-1-(phenylsulfonyl)cyclopropyllithium–Dimethoxyethane (2/3): A Sulfonyl “Carbanion” Having an α-C Atom with a Tetrahedral Configuration

✍ Scribed by Dipl.-Chem. Werner Hollstein; Dr. Klaus Harms; Michael Marsch; Prof. Dr. Gernot Boche


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
271 KB
Volume
27
Category
Article
ISSN
0044-8249

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✦ Synopsis


CpRhFe,(CO),(RC-CR)] has been reported by Vahrenkamp et al.;lX1 in that case, however, the formation of an alkyne ligand by C-C bond formation did not occur.

The cleavage and formation of alkynes coordinated to a cluster has been of great recent interest.