V= 1246.97 A', ecalc= 1.311 g . ~r n -~. From 3154 measured reflections (MoK, radiation, h = 0.71073 A) 2128 with I>2u(Z) were used for the refinement of the structure [R(F) [ "I This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and BASF AG. Ludwiasha
✦ LIBER ✦
X-Ray Structure Analysis of α-Lithiophenylacetonitrile · Lithium Diisopropyl amide· 2 Tetramethylethylenediamine—a “Quasi-Dianion Complex”
✍ Scribed by Dipl.-Chem. Wolfgang Zarges; Michael Marsch; Dr. Klaus Harms; Prof. Dr. Gernot Boche
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 457 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
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Thermal as well as photochemical decomposition of 6 in I ,2-dichloroethylene, styrene or fumarates (as solvent) leads exclusively to the dimers 19 and 20, and even with N-phenylmaleimide the dimerization can only be suppressed with excess of the reagent. Since the ratio of trapping products to dimer