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X-Ray Structure Analysis of 6-Thiatetracyclo-[5.4.0.02.4.03.5]undeca-1(7),8,10-triene

✍ Scribed by Dr. Chizuko Kabuto; Dipl.-Chem. Toshio Tatsuoka; Prof. Dr. Ichiro Murata; Prof. Dr. Yoshio Kitahara


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
225 KB
Volume
13
Category
Article
ISSN
0044-8249

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✦ Synopsis


Arsabenzene-4-carbaldehyde ( 4 ) can be obtained pure as a pale yellow oil by bulb tube vacuum distillation (10-' torr). Surprisingly, the product, which is stable under nitrogen, smells strongly and unmistakably of benzaldehyde, thus providing further justification for the trivial name "arsabenzaldehyde" [


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Crystal Structure of 2,4,5,7,9,10-Hexaox
✍ Prof. Dr. Waldemar Adam; Ernst Schmidt; Dr. Eva-Maria Peters; Dr. Karl Peters; P 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB 👁 1 views

formed separately and the Pe stabilized as a bisphosphane complex['0T. The complex with tris(dimethy1amino)phosphane, the 1,1,1,3,3,3-hexakis(dimethylamino)-l?~~,32.~-triphospha-2-enium tetraphenylborate 2, is particularly easy to handle"']. In order to accept Pe from 2, however, the olefin must be