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X-ray structural and molecular mechanics investigation of cyclopentadienyl-carbonyl-triphenylophosphine-phenylacetyliron, (η5-C5H5)Fe(CO)(PPh3)(COCH2C6H5)

✍ Scribed by J. W. Krajewski; P. Gluziński; A. Zamojski; A. Mishnyov; A. Kemme; Zhong-Wu Guo


Publisher
Springer
Year
1992
Tongue
English
Weight
305 KB
Volume
22
Category
Article
ISSN
1572-8854

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Base-dependent stereoselectivity in reac
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Alkylation of the anion 4 is only little stereoselective und leads to mixtures of stereoisumeric products SA&9A,B. Proportion qf stereoisomers depends strongly on the base employed. Condensation with acetaldehyde or benzaldehyde leads to four stereoisomeric products llC-F and 12C-F, proportion of wh