𝔖 Bobbio Scriptorium
✦   LIBER   ✦

X-ray structural analysis and theoretical studies of new phosphite-derived ylides

✍ Scribed by Mohsen Rostamizadeh; Malek Taher Maghsoodlou; Sayyed Mostafa Habibi-Khorassani; Nourallah Hazeri; Faramarz Rostami Charati; Mohammad Amin Kazemian; Brian W. Skelton; Mohamed Makha

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
341 KB
Volume
22
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction between dialkyl acetylenedicarboxylates and NH heterocyclic compounds in the presence of triethyl phosphite leads to stable phosphorus ylide derivatives in good yields. The X-ray crystallographic data and theoretical study show that there is a resonance between two bonds of C 19 P 1 and C 191 O 191 in phosphorus ylide 4d. This compound crystallizes in the orthorhombic system, space group

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: X-Ray Structural An
ChemInform Abstract: X-Ray Structural Analysis and Theoretical Studies of New Phosphite-Derived Ylides.
✍ Mohsen Rostamizadeh; Malek Taher Maghsoodlou; Sayyed Mostafa Habibi-Khorassani; πŸ“‚ Article πŸ“… 2012 πŸ› John Wiley and Sons βš– 24 KB

## Abstract The reaction between electron‐deficient acetylenedicarboxylates (I), triethyl phosphite (II), and N‐H heterocycles (III) provides access to the stable phosphorus ylides (IV) in high yields.

Molecular structure and theoretical stud
Molecular structure and theoretical studies of new stable phosphorus ylides derived from trialkyl phosphites
✍ Mohsen Rostamizadeh; Malek Taher Maghsoodlou; Sayyed Mostafa Habibi-Khorassani; πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 294 KB

## Abstract The reaction between dialkyl acetylenedicarboxylates and NH heterocyclic compounds in the presence of trialkyl phosphite leads to stable phosphorus ylide derivatives in good yields. The x‐ray crystallographic data and theoretical study show that there is a resonance between two bonds of

Synthesis of new phosphorus ylides: Spec
Synthesis of new phosphorus ylides: Spectroscopic and X-ray structural studies
✍ Seyyed Javad Sabounchei; Parisa Shahriary; Zabiholla Bolboli Nojini; Hamid Reza πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 488 KB

Ar = p-tolyl or phenyl), have been C-acylated by acetic anhydride to obtain new types of phosphorus ylides. Synthesis and characterization of six phosphorus ylides of the type Ar 3 PC(COCH 3 )(COR) are reported. The reaction of {(p-tolyl) and {Ph 3 PCHCOOCH 2 C 6 H 5 } (VI) with acetic anhydride in

Structural studies of bioactivity in sol
Structural studies of bioactivity in sol-gel-derived glasses by X-ray spectroscopy
✍ Skipper, Laura J. ;Sowrey, Frank E. ;Pickup, David M. ;Fitzgerald, Victoria ;Ras πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 116 KB

## Abstract Extended X‐ray absorption fine structure spectroscopy and X‐ray absorption near edge structure, X‐ray fluorescence spectroscopy, and X‐ray powder diffraction have been used to study the local calcium environment in four sol–gel‐derived bioactive calcium silicate glasses of the general f