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X-ray single crystal, spectral, thermal analysis and31P{1H} NMR of ruthenium(II)/ether-phosphine/1,2-diphenyl-1,2-ethanediamine complexes

✍ Scribed by Ismail Warad

Book ID: 120765687
Publisher: Springer Netherlands
Year: 2012
Tongue: English
Weight: 320 KB
Volume: 39
Category: Article
ISSN: 0922-6168
DOI: 10.1007/s11164-012-0706-7

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## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_