The X-ray and W photoemission valence band spectra of NiO are interpreted using the molecular orbital theory for the NiOpcluster and the sudden approsimation (monopole selection rules). They exhibit the effects of crystal field splitting, multiplet splitting, electron shake-up (0 2pe$' -Ni 3dea). re
X-ray photoemission and the electronic structure of solids
β Scribed by G.K. Wertheim
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 686 KB
- Volume
- 298
- Category
- Article
- ISSN
- 0016-0032
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β¦ Synopsis
The principles of X-ray photoelectron spectroscopy are outlined. The application of this technique to the study of the electronic structure of metals, alloy.9 and compounds is illustrated using data in Ag, /3-brass, ReO, and PO,. In the latter a major change in the density of states is observed on passing through the metal-insulator transition.
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