## Abstract There is evidence to suggest that Cu(II) is involved in the natural spinning process of a silkworm helping to convert the concentrated silk fibroin (SF) solution (or dope) into tough insoluble threads. To investigate the interaction between SF and Cu(II), a series of regenerated SF (RSF
X-ray photoelectron spectroscopic study of silk fibroin surface
✍ Scribed by Jianzhong Shao; Jinqiang Liu; Jinhuan Zheng; C M Carr
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 117 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0959-8103
- DOI
- 10.1002/pi.1092
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
X‐ray photoelectron spectroscopy (XPS) has been used to probe the nature of silk fibroin surface, in particular the tyrosine content and sulfur species on the surface. The iodine labelling treatment of silk, followed by XPS surface analysis, reveals that silk fibroin has a tyrosine‐enriched surface, and that there are sulfur‐containing amino acids present on the surface, mainly occurring in the S^6+^ component. UV/ozone treatment modifies/removes the surface tyrosine‐ and sulfur‐containing species.
© 2002 Society of Chemical Industry
📜 SIMILAR VOLUMES
This study was focused on the conformational characterization of Bombyx mori silk Ðbroin in Ðlm, Ðber and powder form by means of Fourier transform Raman spectroscopy. Native and regenerated silk Ðbroin Ðlms prepared by casting dilute silk Ðbroin solutions (AE1% , w/v) display characteristic conform