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X-ray photoelectron spectroscopic study of polynuclear complexes of two “f”-Block elements with metal Schiff base complexes

✍ Scribed by V. Di Castro; I. Fragalà; S. Giuffrida; G. Mattogno


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
266 KB
Volume
12
Category
Article
ISSN
0368-2048

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✍ J. Grimblot; J.P. Bonnelle; A. Mortreux; F. Petit 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 736 KB

X-Ray photoelectron and infrared spectroscopies are used to analyse the electronic displacements on changing the ligands in RhCICOLz complexes, particularly with Ph 3-,, P(N{), (n = I ,2,3) aminophosphines. In the free aminophosphines, a back donation from N to P is shown, whereas in the rhodium com