X-Ray molecular structure and reactions of bis(styrene)bis(triphenylphosphine)ruthenium(0); the first sixteen-electron ruthenium(0) species

Five- and Six-Coordinate Ruthenium(II) C

Five- and Six-Coordinate Ruthenium(II) Complexes Containing the Bidentate Phosphane (−)-N,N-Bis(diphenylphosphanyl)-(S)-1-phenylethylamine [(S)-peap]: X-ray Crystal Structure of the First 16-Electron Ruthenium Complex Bearing a Four-Membered Ring [RuCl{κ2-P,P-(S)-peap}2][SbF6]·C2H4Cl2

✍ Josefina Díez; M. Pilar Gamasa; José Gimeno; Yolanda Rodríguez; Santiago García- 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_