✦ LIBER ✦

X-ray-induced Cu(II) reductions in α-and γ-zirconium phosphates intercalated with copper ions

✍ Scribed by Giovanni Marletta; Orazio Puglisi; Salvatore Pignataro; Giulio Albert; Umberto Costantino

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 359 KB
Volume: 89
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83510-0

No coin nor oath required. For personal study only.

✦ Synopsis

Recewed 24 February 1981; in final form 13 Apnl 1982 Different reduction rates are iound m XPS ew?nmcnls on Cu(ll) IOIIS mrcrabtcd tn CI-and I-Zr(HPOJ)s crys~~lhn~ compounds. Tbls 1s atG%utcd to varhtlon of Ihe ewitomc trdp~mg probxbdlty for 0-O bonds III ddicrcnt crystalbnc snes or to dlfiercnt coordmalion of the mtercahtlon sites ma-and -$r(HP04)2.

📜 SIMILAR VOLUMES

Intercalation compounds of α-zirconium h

Intercalation compounds of α-zirconium hydrogen phosphate with Rh3+ ions and Rh3+-diamine complexes. Part II. Their behaviour towards CO, CO2 and H2 and their use in the CO catalytic oxidation

✍ P. Giannoccaro; A.La Ginestra; M.A. Massucci; C. Ferragina; G. Mattogno 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 924 KB

The reactivity of Rh3+ ions and Rh3+ -diamine CI-ZI(HPOJ~ . H,O complexes intercalated in a-zirconium hydrogen phosphate towards small molecules (CO, 0,, H2) was studied. The compounds only containing Rh3+ ions, of composition ZrH,Rh,(PO,)z .4H,O (X = 2 -3y; 0 < y I 0.66) react with CO at atmospheri