Structural studies of bridgehead alkenes
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K.J. Shea; David K. Cooper; W.P. England; Joseph W. Ziller; Timothy G. Lease
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Article
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1990
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Elsevier Science
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French
β 269 KB
## TheX -ray crystal structure of 3-oxnbicyclo[53.Il&ca-I(1O).7(8)-(zz)-diene-IO-carboxylic acid, a highly strained bridgehead diem?, is reported. Bridgehead alkenes (1) comprise a subclass of trarrscycloallcenes ( 2), compounds that contain a distorted carbon-carbon double bond.' The magnitude of