X-ray diffraction structural study of 1,7-dimethyl-1,7-dioxa-2,3,5,6-tetraaza-2.5-heptadiene 3,5-dioxide
β Scribed by V. D. Cherepinskii-Malov; G. A. Marchenko; A. S. Mukhametzyanov; B. I. Buzykin
- Book ID
- 112442487
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 78 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The title compound, C 12 H 14 N 6 , was synthesized via cyclocondensation of 5-guanidino-3-phenyl-1,2,4-triazole with acetone. Only one tautomeric form with the NH H atom vicinal to the methyl groups was observed in the crystal structure. The triazine ring adopts a flattened half-boat conformation.
## Abstract A novel synthesis of substituted thieno[3,2β__c__]azepinones is described. This new approach uses 5,5βdimethylβ1,3βcyclohexanedione (dimedone) as the starting material. Oxime intermediates are obtained in three steps from the aforementioned diketone. Using these intermediates, the title