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X-ray diffraction measurement of the Jahn-Teller distortion in TmVO4

✍ Scribed by Armin Segmüller; R.L. Melcher; H. Kinder


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
269 KB
Volume
15
Category
Article
ISSN
0038-1098

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Jahn-Teller distortion and electronic st
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The O-ccntcr in CaFa is invcstisatcd by performing multiple scattcrirq Xa calculations on the (Ore)'-cluster. In agreement with cxpcrimcnt, a strong Jahn-Teller distortion of tctrqondl symmetry is prcdictcd. Finally the ground state electronic structure of the cluster is discussed.

Jahn-Teller distortion in the excited st
✍ P.J.H. Drummen; H. Donker; W.M.A. Smit; G. Blasse 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 237 KB

The luminescence spectra of the diluted systems CszZrClb: Te4+ and Cs#Q,: Te4+ are reported at liquid-helium and room temperature. The shape of the excitation spectrum of the Te 4+ luminescence reveals a dynamic Jahn-Teller distortion in the excited state. At low temperatures the Te4+ emission shows